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(Mesitylene)molybdenum tricarbonyl
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(Mesitylene)molybdenum tricarbonyl is an organomolybdenum compound derived from the aromatic compound mesitylene (1,3,5-trimethylbenzene) and molybdenum carbonyl. It exists as pale yellow crystals, which are soluble in organic solvents but decompose quickly when in solution. It has been examined as a catalyst and reagent.
==Synthesis==
(Mesitylene)molybdenum tricarbonyl arises from the reaction of molybdenum hexacarbonyl with hot mesitylene:
:Mo(CO)6 + (CH3)3C6H3 → Mo(CO)3() + 3 CO
It can also be synthesized, with good yields by displacement of pyridine ligands of the trispyridine complex Mo(CO)3(pyridine)3 in the presence of Lewis acids. This reaction proceeds at lower temperatures of the compound than the direct method
:Py3Mo(CO)3 + (CH3)3C6H3 + 3BF3·O(C2H5)2 → ()Mo(CO)3 + 3PyBF3
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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